Why is expansion upon freezing important




















It is this open solid structure that causes ice to be less dense than liquid water. That is why ice floats on water, for which we should all be thankful because if water behaved "normally" many bodies of water would freeze solid in the winter, killing all the life within them. Water's "density maximum" is a product of the same phenomenon. Close to the freezing point, the water molecules start to arrange locally into ice-like structures.

The answer to your question is that, in general, a given volume of liquid water at room temperature will increase in volume by about 9.

It is less dense than the liquid form of water above since this crystal structure takes up more volume than the free-to-move-around liquid water molecules. Because the bonds between water molecules are stronger, they are less likely to break and re-form as they do in the liquid state. As a liquid, water molecules are constantly moving forming and breaking hydrogen bonds resulting in less expansion.

If ice was heavier than water , whenever it froze , it would sink to the bottom, and eventually, since the top layer would insulate the ice, virtually the entire body of water would freeze solid. Lakes, rivers, and perhaps even oceans would mostly freeze solid. What do you think happens to water molecules when liquid water changes to solid ice?

Water is unusual because its molecules move further apart when it freezes. The molecules of just about every other substance move closer together when they freeze. Water's Absorption of Heat[edit] Water is able to resist temperature changes due to hydrogen bonding. Specifically, in order for water to increase in temperature hydrogen bonds must break giving rise to the relatively high boiling point of water. This sticking together of like substances is called cohesion. Depending on how attracted molecules of the same substance are to one another, the substance will be more or less cohesive.

Hydrogen bonds cause water to be exceptionally attracted to each other. Therefore, water is very cohesive. The Expansion of Water Upon Freezing. The fact that water expands upon freezing causes icebergs to float. Freezing happens when the molecules of a liquid get so cold that they slow down enough to hook onto each other, forming a solid crystal.

Hydrogen bonds form and break like high school relationships, that is to say, quickly. But below 4 degrees, the kinetic energy of the water molecules starts to fall below the energy of the hydrogen bonds. So, hydrogen bonds form much more frequently than they break and beautiful structures start to emerge from the chaos.

This is what solid water, ice, looks like on the molecular level. Notice that the ordered, hexagonal structure is less dense than the disordered structure of liquid water. And you know that if an object is less dense than the fluid it's in, it will float. So, ice floats on water, so what? Well, let's consider a world without floating ice. The coldest part of the ocean would be the pitch-black ocean floor, once frozen, always frozen.

Forget lobster rolls since crustaceans would lose their habitats, or sushi since kelp forests wouldn't grow. What would Canadian kids do in winter without pond hockey or ice fishing? Once it gets cold enough around 32 degrees Fahrenheit , the expanding water molecules begin to form ice crystals. This spreading-out of water molecules as it freezes is why sometimes a bottle full of water will break when you freeze it. The fact that water expands when frozen is also really important to life on Earth.

Because it expands, ice takes up more space than water it is less dense. This causes the ice to float on water. Though it may be hard to imagine, this layer of ice actually helps to keep fish, other animals and plants warm in ponds and lakes during the winter.



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